For , standard reduction potential = + 0.54 volt. For , standard oxidation potential = – 1.09 volt. For standard oxidation potential = + 0.44 volt. Which of the following reactions is non-spontaneous?
A redox reaction in which SRP of oxidising agent is lesser than SRP of reducing agent is non-spontaneous and does not occurs.
Alternatively, If Ecell comes to be negative the reaction is non-spontaneous and does not occur.
For option (4), E0= E0(Cathode)-E0(anode)= +0.54V-1.09V=-0.55V ;