Q.
(I) H3PO2 , (II) H3PO3 (III) H3PO4Correct increasing order of acidic strength () is
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a
I , II , III
b
II , I , III
c
III ,I , II
d
III , II , I
answer is D.
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Detailed Solution
structure of conjugate bases of I , II , III respectively (A) (B) (C)Consider (A) Equivalent (indistinguishable) structures maximum dispersal of negative chargeconsider (B) : possibility (I) Possibility (II) Thus structure (B) is less stable as compared to (A)Consider (C) : possibility (I) Possibility (II) Possibility (III) (C) is much more unstableThus stability of H3PO2- > H2PO3- > H2PO4-Other explanation:-I effect of P=O group is distributed only on one -OH in H3PO2 where as on two -OH groups in H3PO3And three -OH groups in H3PO4
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