For an ideal binary liquid solution with pAo>pBo. xA and yA represent the mole fraction of A in liquid phase and vapour phase respectively whereas xB and yB represents the mole fraction of B in liquid phase and vapour phase respectively. Therefore which of the following relation is correct?
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a
xA=yA
b
xA>yA
c
xAxB
d
xAxB>yAyB
answer is C.
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Detailed Solution
P'A=PA0 xA=psol × yAP'B=poxB=psol×yB∴YAYB=PAoPBo×XAXB Since pAo>pBo∴YAYB>XAXB