Q.
An ideal solution is formed by mixing two volatile liquids A and B. XA and XB are the mole fractions of A and B respectively in the solution and Yo and Y, are the mole fractions of A and B respectively in the vapour phase. A plot of 1YAalong y-axis against, along x-axis gives a 1XAstraight line. What is the slope of the straight line ?
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a
PB∘PA∘
b
PA∘PB∘
c
PB∘−PA2
d
PA∘−PB∘
answer is A.
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Detailed Solution
yA=PA∘xAPA∘xA+PB∘xB=PA∘xAPB∘+PA∘−PB∘xA 1yA=PB∘xB+PA∘xAPA∘xA=1+PB∘PA∘1−xAxA =1−PB∘PA∘+1xAPB∘PA∘ ∴ Slope =PB∘PA∘
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