Q.

Identify the correct statements from the followingA) Dipole moment of CH3F > CH3ClD) C-X bond length in CH3F > CH3Cl

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a

A, B and C only

b

A, B and D only

c

C only

d

B only

answer is D.

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Detailed Solution

A) Dipole moment of CH3F < CH3Cl.Though C-F bond is more polar the C-Cl bond, C-Cl bond  is much longer than C-F bond.We know , µ = e × d. Product of e×d is higher for methyl chloride.∴µ of CH3Cl > CH3F.B) p- isomer is symmetrical, it has higher melting point.C) o-isomer is more polar, it has higher boiling point.D) C-F bond is shorter than C-Cl bond.
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