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Q.

Identify the most stable carbocation from the following species

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a

b

c

d

answer is C.

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Detailed Solution

-CH3 gp -+I, +R effect at para position-EDG; -Cl     gp--I, -M effect at para position-EWG; -M effect is negligble -NO2 gp -       -I, -M effect  at  para position-EWG; -NO2>-Cl........EW power; EDG increases the stability of carbocation by dispersing the positive charge; EWG decreases the stability of carbocation by intensifying the positive charge;
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