Q.
Identify the reaction from following having top position in EMF series (Std. red. potential) according to their electrode potential at 298 K.
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a
K++1e−→K(s)
b
Mg2++2e−→Mg(s)
c
Fe2++2e−→Fe(s)
d
Au3++3e−→Au(s)
answer is D.
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Detailed Solution
Au3++3e−→Au(s) E∘=1.40VFe2++2e−→Fe(s) E∘=−0.44VMg2++2e−→Mg(s) E∘=−2.36VK++1e−→K(s) E∘=−2.93VAs per electrochemical series, Au3+ occupies the top position.
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