Q.

Identify the reaction from following having top position in EMF series (Std. red. potential) according to their electrode potential at 298 K.

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a

K++1e−→K(s)

b

Mg2++2e−→Mg(s)

c

Fe2++2e−→Fe(s)

d

Au3++3e−→Au(s)

answer is D.

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Detailed Solution

Au3++3e−→Au(s)    E∘=1.40VFe2++2e−→Fe(s)    E∘=−0.44VMg2++2e−→Mg(s)    E∘=−2.36VK++1e−→K(s)    E∘=−2.93VAs per electrochemical series, Au3+ occupies the top position.
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