Q.

If CuSO4. 5H2O(s)  ⇌  CuSO4. 3H2O(s)  +  2H2O(l)  KP= 1.086  ×  10-4 atm2 at 250C. The efflorescent nature of CuSO4. 5H2O can be noticed when vapour pressure of H2O in atmosphere is

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a

>7.29 mm

b

<7.92 mm

c

≥ 7.92 mm

d

None

answer is B.

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Detailed Solution

An efflorescent salt is one that loses H2O to atmosphere.For the reactionCuSO4. 5H2O(s)  ⇌  CuSO4. 3H2O(s)  +  2H2O(l)KP= pH2O'2= 1.086 × 10-4 pH2O'= 1.042 × 10-2 atm=7.92 mm∵    If   pH2O'  at  250C < 7.92 mm only, then reaction will proceed in forward direction.
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