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Q.

If equal volume of 1M KMnO4 and 1M K2Cr2O7 solutions are allowed to oxidize Fe(II) to Fe(III) in acidic medium, then Fe(II) oxidize will be:

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a

More by KMnO4

b

More by K2C2O7

c

Equal in both cases

d

Can't be determined

answer is B.

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Detailed Solution

5e−+KMnO4⟶Mn2+6e−+K2Cr2O7⟶2Cr3++6e−Fe2+⟶Fe3++e−5 mole of Fe2+ oxidize by 1 mole of KMnO46 mole of Fe3+ oxidize by 1 mole of K2Cr2O7
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If equal volume of 1M KMnO4 and 1M K2Cr2O7 solutions are allowed to oxidize Fe(II) to Fe(III) in acidic medium, then Fe(II) oxidize will be: