If 0.44 g of a colourless oxide of nitrogen occupies 224 mL at 1520 mm Hg and 273°C , then the compound
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a
NO
b
NO2
c
N2O3
d
N2O
answer is D.
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Detailed Solution
P1=1520mm, V1=224mL, T1=273+273=546K At N.T.P. : P2=760mm, V2=?,T2=273K. Applying gas equation, we have : P1V1T1=P2V2T2Substituting the values, we get :V2=1520×224×273760×546=224mL.Thus 224mL oxide of nitrogen weighs =0.44g∴22400mL weighs =0.44224×22400=44g ∴ Gram molar mass of oxide of nitrogen=44 Gas =N2O because molar mass of N2O=(2×14)+16=44.