If the ionic product of Ni(OH)2 is 1 .9 x 10-15, then the molar solubility of Ni(OH)2 in 1.0 M NaOH is
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a
1.9×10−18 M
b
1.9×10−13 M
c
1.9×10−11 M
d
1.9×10−14 M
answer is C.
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Detailed Solution
NaOH⇌Na++OH− CM CMNi(OH)2⇌Ni2++2OH− X X X Total OH−=x+C ∴Ksp=Ni2+OH−2=x(x+C)2 =xx2+2Cx+C2 or Ksp=xC2 (neglecting higher powers of x ) x=KspC2=1.9×10−15(1)2=1.9×10−15M