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Q.

If rate constant is numerically the same for three reactions of first, second and third order respectively. Which of the following is correct?

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a

if [A]=1 then r1=r2=r3

b

if [A]<1 then r1>r2>r3

c

if [A]>1 then r3>r2>r1

d

All

answer is D.

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Detailed Solution

Rate law for 1st order2nd order3rd orderR1=K[A]1R2=K[A]2R3=K[A]3If  [A]=1 Then    r1=r2=r3 [A]<1   then    r1>r2>r3[A]>1   then   r3>r2>r1
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If rate constant is numerically the same for three reactions of first, second and third order respectively. Which of the following is correct?