Q.

If Xm, Xp and XV represent mole, pressure and volume fractions respectively, then

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a

Xm=Xp=XV

b

Xm=1Xp=1XV

c

Xm=Xp=1XV

d

1Xm=1Xp=XV

answer is A.

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Detailed Solution

n1= moles of component I p1V1RT1=p1V1RT n2= moles of component II p2V2RT2=p2V2RT Xm (of component I) =n1n1+n2=p1V1p1V1+p2V2                                       =V1V1+V2=XV at constant p                                          =p1p1+p2=Xp at constant V Hence,                              Xm=XV=Xp
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