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Q.

If x1, x2 and x3 are enthalpies of H-H, O = O and O-H bonds respectively, and x4 is the enthalpy of vaporisation of water, estimate the standard enthalpy of combustion of hydrogen.

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a

x1+x22-2x3+x4

b

x1+x22-2x3-x4

c

x1+x22-x3-x4

d

2x3-x1-x22-x4

answer is B.

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Detailed Solution

H2g+12 O2g →H2Ol ;     ∆Hcomb,  H2 ∆Hcomb=∆HH-H+12∆HO2 -2∆HOH-∆Hvap = x1+x22-2x3-x4
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If x1, x2 and x3 are enthalpies of H-H, O = O and O-H bonds respectively, and x4 is the enthalpy of vaporisation of water, estimate the standard enthalpy of combustion of hydrogen.