Q.

The impure  CHCl3 gives a white ppt when its treated with  solution. AgNO3    Its due to

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a

COCl2

b

Cl2

c

HCl

d

All

answer is C.

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Detailed Solution

Chloroform undergo oxidation and give a poisonous Phosgene along with HCl.  The formed HCl reacts with AgNO3CHCl3  +  12 O2  →  COCl2  + HClAgNO3  +  HCl  →  AgCl ↓  +  HNO3                                                white  ppt
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The impure  CHCl3 gives a white ppt when its treated with  solution. AgNO3    Its due to