Q.

The increasing order of boiling points of the following compound is

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a

III < I < II < IV

b

I < IV < III < II

c

IV < I < II < III

d

I < III < IV < II

answer is B.

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Detailed Solution

I)  P-cresol                          202ºCII) P-nitro phenol                279ºCIII) P-aminophenol             284ºCIV) P-methoxy phenol        243ºCDue to hydrogen bonding B.pt of P-amino phenol is high in other cases grater the ‘u’, greater is the B.pt III > II > IV > I
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The increasing order of boiling points of the following compound is