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Q.

The increasing order of stability of the following free radicals is:

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a

CH32C•H

b

C6H53C• 

c

C6H52C•H

d

CH32C•H

answer is A.

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Detailed Solution

C6H53C•Tertiary , C6H52C∙HSecondary  are more stable due to resonance.Stability of CH33C•tertiary  and CH32C•HSecondary  is due to hyperconjugation.Tertiary is always more stable than secondary free radical.
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