Q.

Inter molecular forces between two benzene molecules are nearly of same strength as those between two toluene molecules. For a mixture of benzene and toluene, which of the following are not true?

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ΔmixH=0

ΔmixV=0

These will form minimum boiling azeotrope

These will not form an ideal solution

answer is C.

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Detailed Solution

Benzene and toluene form ideal solution and for an ideal solution inter molecular forces between two benzene molecules are nearly of same strength as those of betweentwo toluene molecules. For such solutions, ΔVmix =0 and ΔHmix =0Azeotropes are formed only by non-ideal solutions.

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