First slide
Crystal lattices and unit cells
Question

Ionic solid Na+ A- crystallise in rock salt type structure. 2.592 gm of ionic solid salt NaA dissolved in water to make 2 litre solution. The pH of this solution is 8. If distance between cation and anion is 300 pm, calculate density of ionic solid (in gm/cm3) .

 (Given : pKw=13,pKa(HA)=5,NA=6×1023 ) 

Moderate
Solution

NaA is salt of SB and WA

pH=pKw2+12pKa+logc8=6.5×12(5+logc)1.5×2=5+logclogc=2c=0.01=2.592M×2M=2.5922×0.01=129.6D=ZMNAa3 Z=4=4g/cm3 a=2×300=600pm

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