The ionisation energy of hydrogen atom is 13.6 eV and the first ionisation energy of helium is 24.6 eVWhat is the first ionisation energy of He+ (isoelectronic of H-atom)?What is the enthalpy change of the following process He2+(g)+2e−⟶He(g)To which of the following species the above formulae or concept is inapplicable
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Detailed Solution
IHgg→ H+g+e− IEH=13.6 eVIIHgg→ He+g+e− IEHefirst=24.6 eVIIIHe+g→ He2+g+e− IEHesecond=?=qBy Bohr's theory of H-atomIEz=IEH=Z2n2IEHe+=13.62212= 54.4 eV Heg→ He2+g+2e−ΔH=24.6+q=79.0 eVHence for He2+g+2e−→ HegΔH=−79.0 eVNote : Second ionisation energy He(g) is the first ionisation of He+ (g).Heg→ He+g+e−IE1 of HegHe+g→ He2+g+e−IE2 of HegIE1 of He+ gBoron has five electrons and +3 means it has now two electron, the concept is mainly applicable to one electron species.
The ionisation energy of hydrogen atom is 13.6 eV and the first ionisation energy of helium is 24.6 eVWhat is the first ionisation energy of He+ (isoelectronic of H-atom)?What is the enthalpy change of the following process He2+(g)+2e−⟶He(g)To which of the following species the above formulae or concept is inapplicable