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Ionization enthalpy of sodium = 492 kJ/mole;

Electron gain enthalpy of chlorine = -349 kJ/mole;

Sublimation enthalpy of sodium = +108 kJ/mole ;

Bond dissociation enthalpy of chlorine = +243 kJ/mole ;

Change in enthalpy for the process, Nas+12Cl2gNa+g+Cl-g will  be

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a
+475 kJ
b
+372.5 kJ
c
+143 kJ
d
+324 kJ

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detailed solution

Correct option is B

Nas→Nag,          ∆H=+108 kJ...............1 Nag→Na+g+e, ∆H=+492 kJ................2 12Cl2g→Clg,      ∆H=+121.5 kJ/mole....3 Clg+e→Cl-g,    ∆H=-349 kJ................4 Adding 1 ,2, 3and 4 Nas+12Cl2g→Na+g+Cl-g, ∆H=+372.5 kJ ;

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