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Q.

Irrespective of +I or -I group the nature of substituent the basic nature of every ortho- substituted aniline will be

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a

Lower than Aniline

b

Greater than aniline

c

Equal to aniline

d

Cannot be predicted

answer is A.

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Detailed Solution

Whether the substituent is EDG OR EWG, every ortho - substituted aniline is less basic than aniline due to steric effect.
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Irrespective of +I or -I group the nature of substituent the basic nature of every ortho- substituted aniline will be