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Q.

In an irreversible process taking place at constant P and T in which only pressure volume work is being done by the system the change in Gibb's energy ∆G and change in entropy ∆S, satisfy the criterion

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a

∆SV.U=0,  ∆GT,P=0

b

∆SV.U=0,  ∆GT,P=+ve

c

∆SV.U=-ve,  ∆GT,P=-ve

d

∆SV.U=+ve,  ∆GT,P=-ve

answer is D.

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Detailed Solution

For a spontaneous change (work is being done by the system) dGT,P=-ve  and dSV,U=+ve
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