Q.

Isostructural species are these which have the same shape and hybridisation. Among the given species identify the isostructural pairs.

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a

[NF3 and BF3]

b

BF4−and NH4+

c

BCl3 and BrCl3

d

NH3 and NO3−

answer is B.

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Detailed Solution

Both are AB4 type of molecules and have the following shape.
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Isostructural species are these which have the same shape and hybridisation. Among the given species identify the isostructural pairs.