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Q.

It is because of inability of ns2 electrons of the valence shell to participate in bonding that

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a

Sn2+ is oxidising while Pb4+ is reducing

b

Sn2+ and Pb2+ are both oxidising and reducing

c

Sn4+ is reducing while Pb4+ is oxidising

d

Sn2+ is reducing while Pb4+ is oxidising.

answer is D.

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Detailed Solution

The inertness of s -subshell electrons towards bond formation is known as inert pair effect. This effect increases down the group thus, for Sn, +4 oxidation state is more stable, whereas, for Pb,+2 oxidation state is more stable, i.e., Sn2+is reducing while Pb4+ is oxidising.
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It is because of inability of ns2 electrons of the valence shell to participate in bonding that