First slide
Applications of Kohlraush law
Question

At 298 K, molar conductance of 0.1 M weak monoacidic base (BOH) is 45 mho.cm2.mole-1. Molar conductance of BOH at infinite dilution is 450 mho.cm2.mole-1. pH of deci molar solution of BOH is

Moderate
Solution

According to Kohlrausch law,

Degree of ionization of BOH, α=ΛcΛ0 ; Degree of ionization of BOH, α=45450=0.1 ; OH- = ; OH- =0.1×0.1=0.01 M;      pOH=2 ;        pH=12 ; 

 

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