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Q.

At 300 K, osmotic pressure of a deci molar solution of Sodium sulphate was observed to be 3.695 atmospheres. Degree of ionization of Sodium sulphate is

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a

0.25

b

0.5

c

0.75

d

0.66

answer is A.

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Detailed Solution

π=iCST; 3.695=i0.1M0.0821×300;          i=3.6950.1×0.0821×300=1.5 ;          i=1-α+nα;          i=1-α+3α;      1.5=1+2α;         α=0.25;
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