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Q.

Ksp of AgCl=1.0×10−10. Select the incorrect statement(s).

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a

pAg+pCl=10

b

pCl=8 in 0.01M Ag+

c

pAg+pCl<10 in presence of Ag+

d

pAg=pCl=5 in saturated AgCl solution

answer is C.

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Detailed Solution

Ag+Cl−=Ksp=1×10−10  ∴ pAq+pCl=10Hence, (a) is true. In 0.01 M Ag+, Cl−=1×10−100.01=1×10−8∴ pCl=8Hence, (b) is true. In all cases pAq+pCl=10 for AgCl at a given temperature. Thus, (c) is incorrect.Since, Ag+=Cl−∴ Ag+=Cl−=Ksp=10−5M log⁡Ag+=log⁡Cl−=−5 −log⁡Ag+=−log⁡Cl−=5 pAg=pCl=5 Hence, (d) is also true.
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