First slide
Standard EMF of a cell
Question

At 298 K the standard reduction potentials for the following half reactions are given as

\large Z{n^{2 + }}_{\left( {aq} \right)} + \,2{e^ - }\, \to \,Z{n_{\left( s \right)}};\, - 0.762\,V

\large C{r^{3 + }}_{\left( {aq} \right)} + \,3{e^ - }\, \to \,C{r_{\left( s \right)}};\, - 0.740\,V

\large 2{H^ + }_{\left( {aq} \right)}\, + \,2{e^ - }\, \to \,{H_{2\left( g \right)}};\, - 0.00\,V

\large F{e^{3 + }}_{\left( {aq} \right)}\, + \,{e^ - }\, \to \,F{e^{2 + }}_{\left( {aq} \right)};\, + 0.770\,V

The strongest reducing agent is

Easy
Solution

E_{{M^{ + n}}_{\left( {1M} \right)}/M}^o\,value\,\,is\,\,low

Right hand species readily undergoes oxidation and is strong reducing agent.

E_{{M^{ + n}}_{\left( {1M} \right)}/M}^o\,value\,\,is\,\,high

Left hand species readily undergo reduction and is strong oxidising agent

Among the given SRP values Zn  electrode is having  lowest value. The right hand species  Zn is readily undergoing oxidation and is strong reducing agent.

Order is

Zn > Cr > {H_2} > F{e^{ + 2}}

Among the given SRP values Fe electrode is having highest value. The left hand species Fe+3 readily undergoes reduction and is strong oxidizing agent.

Order is

Fe+3 >H+ >Cr+3 >Zn+2

 

 

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