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The key step in the manufacture of H2SO4 is
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a
burning of sulphur or sulphide ores in air to generate SO2
b
catalytic oxidation of SO2 with O2 to give SO3 in the presence of V2O5
c
absorption of SO3 in H2SO4 to give oleum
d
Either (b) or (c)
answer is D.
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Detailed Solution
The key step in the manufacture of H2SO4 is 2SO2(g)+O2(g)→V2O52SO3(g);ΔrH∘=−196.6kJ mol−1This reaction is endothermic, reversible and the forward reaction leads to a decrease in volume. Thus, low temperature and high pressure are the favourable conditions for maximum yield. But the reaction should not be very low other wise rate of reaction will become slow.
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