The Kjeldahl method of Nitrogen estimation fails for which of the following reaction products?
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a
(b) and (c)
b
(a), (c) and (d)
c
(c) and (d)
d
(a) and (d)
answer is C.
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Detailed Solution
Nitro benzene on reduction with Sn + HCl gives Aniline. Nitrogen is attached to carbon and hydrogen. Nitrogen can be estimated by using kjeldahl’s methodIn a compound Nitrogen attached to both carbon and hydrogen, nitrogen can be estimated by Kjeldahl’s method.C) Benzyl cyanide on reduction with Sn+HCl and followed by hydrolysis gives aldehyde.Resultant compound no nitrogen temperature gives diazonium in this reaction final product is phenol no nitrogen in the resultant compound.