The Langmuir adsorption isotherm is deduced using the assumption:
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a
The adsorption sites are equivalent in their ability to adsorb the particles
b
The heat of adsorption varies with coverage
c
The adsorbed molecules interact with each other
d
The adsorption takes place in multilayers
answer is A.
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Detailed Solution
Langmuir adsorption isotherm is valid for monolayer chemical adsorption. Having adsorption sites at active centers, i.e., free valencies which have equivalent ability to adsorb the particles.