Lassaigne's extract of an organic compound when heated with sodium nitroprusside gives a Violet coloured ‘X’. ‘X’ is
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a
Na4FeCN5NOS
b
Fe4FeCN63
c
Fe3FeCN62
d
Na2FeCN5NO
answer is A.
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Detailed Solution
This is a test to identify sulphur present in organic compound.Sulphur in sodium fusion extract or Lassaigne's extract exists as Na2S.Na2S + Na2FeCN5NO → Na4FeCN5NOS Sod.nitroprusside Violet colour