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Q.

Lassaigne's extract of an organic compound when heated with sodium nitroprusside gives a Violet coloured  ‘X’.   ‘X’  is

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a

Na4FeCN5NOS

b

Fe4FeCN63

c

Fe3FeCN62

d

Na2FeCN5NO

answer is A.

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Detailed Solution

This is a test to identify sulphur present in organic compound.Sulphur in sodium fusion extract or Lassaigne's extract exists as Na2S.Na2S + Na2FeCN5NO →  Na4FeCN5NOS                Sod.nitroprusside              Violet colour
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