Q.
In Lassaigne’s test for nitrogen, the Blue color is due to the formation of
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a
Sodium cyanide
b
Potassium hexacyano ferrate (II)
c
Ferrous ferro cyanide
d
Iron (III) hexacyano ferrate (II)
answer is D.
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Detailed Solution
When nitrogenated lassaigne’s filtrate is treated with freshly prepared ferrous sulphate solution and dilute sulphuric acid will give Prussian Blue.Na+C+N→fuseNaCNFeSO4+2NaOH→FeOH2+Na2SO4FeOH2+2NaCN→FeCN2+2NaOHFeCN2+4NaCN→Na4FeCN63Na4FeCN6+4Fe+3→Fe4FeCN63+12Na+ Iron(III) hexacyano ferrate(II)
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