The law of multiple proportion is illustrated by the two compounds :
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a
Sodium chloride and sodium bromide
b
Ordinary water and heavy water
c
Caustic soda and caustic potash
d
Sulphur dioxide and sulphur trioxide
answer is D.
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Detailed Solution
When two different elements combines to form two or more compounds, the weight of of one element combined with fixed weight of the other are in the ratio of small whole numbers.Weight of oxygen combining with 1 gm (fixed) Sulphur is 3232:4832 = 2 : 3