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Q.

The length of a unit cell (a) in the Ni crystal is 0.352 nm. The diffraction of X-rays of 0.154 nm wavelength (λ) from a Ni crystal occurs at 22.2°,25.9°, and 38.2°. By using Bragg's law, (nλ = 2d sin θ), and assuming that the diffractions are first order (n = 1),the distances are calculated to be 0.204 nm, 0.176nm and 0.124 nm. The various structures for the Ni crystal are represented as:If the distance (d) is 0.204 nm represent which structure?The distance (d) of 0.176 nm represent which structure?The distance (d) of 0.124 nm represent which structure?

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Detailed Solution

The distance 0.204 nm comes out to be "a/3 "  which corresponds to the perpendicular distance between a corner of unit cell and the plane of the three adjacent corners.The distance 0.176 nm is half the unit cell length (a/2) which corresponding to the perpendicular distance between the layers of atoms in one face of the unit cell and the center (Fig. I)The distance 0.124nm corresponds to 2/4 times the unit cell dimension, i.e., one-fourth of the distance from one edge of the cell to the opposite edge (Fig. II). The plane intersects the face-centered atoms of the two sides. The plane including the edge atoms is equivalent to the plane across the center of the unit cell.
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The length of a unit cell (a) in the Ni crystal is 0.352 nm. The diffraction of X-rays of 0.154 nm wavelength (λ) from a Ni crystal occurs at 22.2°,25.9°, and 38.2°. By using Bragg's law, (nλ = 2d sin θ), and assuming that the diffractions are first order (n = 1),the distances are calculated to be 0.204 nm, 0.176nm and 0.124 nm. The various structures for the Ni crystal are represented as:If the distance (d) is 0.204 nm represent which structure?The distance (d) of 0.176 nm represent which structure?The distance (d) of 0.124 nm represent which structure?