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Quantum mechanical model of the atom

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By Expert Faculty of Sri Chaitanya
Question

The letters n, I and m proposed by Bohr, Sommerfeld and Zeeman respectively for quantisation of angular momentum in classical physics were later on obtained as the results of solution of Schrödinger wave equation based on quantum mechanics. The term n, l, m were named as principal quantum number, azimuthal quantum number and magnetic quantum number respectively. The fourth quantum number i.e., spin quantum number, s was given by Uhlenback on the basis of two spins of electrons. The first two quantum numbers also decides the nodes of an orbital. 

Moderate
Question

 The numerical value Ψ4,3,0 denotes : 

Solution

Ψ represents an orbital and Ψ4,3,0 has n=4,l=3, i.e., 4f-orbital. 

Question

 The angular momentum of 3p-orbitals in terms of ħħ=h2π is: 

Solution

 Angular momentum in an orbital =l(l+1)h2π=1(1+1)h2π=2ħ

Question

Which statement about energy level in H-atom is correct? 

Solution

all Sub-shells of a shell in H-atom possess same energy level, i.e.,( l ) does not specify for the energy level of an orbital in H-atom. 


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