Q.

The liquid mixture which shows positive deviations from Raoult's law is

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a

Phenol + Aniline

b

Nitric acid + Water

c

Acetone + Chloroform

d

Acetone + Carbondisulphide

answer is D.

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Detailed Solution

The liquid mixture which shows positive deviations from Raoult's law is  CH3COCH3+CS2;Dipole-dipole attractions in Acetone are disturbed by the addition of non polar carbondisulphide molecules. A-B interactions are weaker than A-A and B-B interactions.
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