The liquid mixture which shows positive deviations from Raoult's law is
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a
Phenol + Aniline
b
Nitric acid + Water
c
Acetone + Chloroform
d
Acetone + Carbondisulphide
answer is D.
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Detailed Solution
The liquid mixture which shows positive deviations from Raoult's law is CH3COCH3+CS2;Dipole-dipole attractions in Acetone are disturbed by the addition of non polar carbondisulphide molecules. A-B interactions are weaker than A-A and B-B interactions.