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Q.

The lone pairs in ClF3 and SCl4 are present respectively at

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a

Axial, axial

b

Axial, equatorial

c

Equatorial, axial

d

Equatorial, equatorial

answer is D.

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Detailed Solution

lone pairs occupy equatorial positions, when lone pair occupies axial position it experiences three 90° repulsions.When lone pair occupies equtorial position it experiences anly two 90° repulsions∴ lone pairs in ClF3 and SF4 occupy equatorial positions.
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The lone pairs in ClF3 and SCl4 are present respectively at