Q.

At low pressure, the Vander Waals equaion is reduced to

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a

Z=pVmRT=1−apRT

b

Z=pVmRT=1+bRTp

c

pVm=RT

d

Z=pVmRT=1−aRT

answer is A.

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Detailed Solution

When pressure is low P+aV2(V−b)=RT or PV=RT+Pb−aV+abV2 or PVRT=1−aVRTZ=−aVRT∵PVRT=Z
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At low pressure, the Vander Waals equaion is reduced to