Q.

Lowering of vapour pressure of an aqueous solution of a non-volatile, non-electrolyte 1 M aqueous solution at 100oC is

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a

14.12 torr

b

312 torr

c

13.45 torr

d

352 torr

answer is C.

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Detailed Solution

1 M aqueous solution contains 1 mole of solute in 1000 g (55.5 moles) of water.                       xB=11+55.5=156.5                                      po=760 torr at 100oC                             ∆ppo=xB,∆p=poxB=760×156.5=13.45 torr
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Lowering of vapour pressure of an aqueous solution of a non-volatile, non-electrolyte 1 M aqueous solution at 100oC is