Q.
0.004 M solution of Na2SO4 is isotonic with 0.01M solution of glucose at same temperature. The approximate degree of dissociation of Na2SO4 is
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a
50%
b
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c
75%
d
85%
answer is C.
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Detailed Solution
For isotonic solutions i1C1 = i2C2Na2SO4 Glucosei1 = ? i2 = 1C1 = 0.004M C2 = 0.01M i1C1 = i2C2 i1 (0.004) = i2(0.01) i1 = 2.5Na2SO4⇌2Na+ +SO4-2n=3i = 1+α(3-1)2.5 = 1+2αα=1.52=0.75
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