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Q.

Match the coloured inorganic compounds in List I with the appropriate phenomenon responsible for the colour in List II

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a

b

c

d

answer is A.

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Detailed Solution

PbI2 is coloured due to polarization of iodide ion by Pb2+CAN is coloured due to Ligand to metal CT. It has no electrons in f-orbitals.  CuSO4.5H2O is a complex and exhibits colour due to d-d transition.Permanganate is coloured due to CT between oxygen and Mn.PrCl3 has incompletely filled f-orbitals and hence exhibits colour due to f-f transition.
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