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a
I-D, II- C, III- B, IV- A
b
I-B, II- A, III- C, IV- D
c
I-A, II- D, III- B, IV- C
d
I-C, II- A, III- B, IV- D
answer is A.
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Detailed Solution
Colour of the complex depends on the nature and charge of metal ion, strength of ligand.NiH2O6+2greenaq+enaq⇌NiH2O4en+2paleblueaq+2H2ONiH2O4en+2 aq+enaq⇌NiH2O2en2+2blue / purpleaq+2H2ONiH2O2en2+2 aq+enaq⇌Nien3+3violetaq+2H2OCrH2O6Cl3 is violet; CrH2O5ClCl2.H2O is grey−green