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Crystal field theory

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By Expert Faculty of Sri Chaitanya
Question

Match the following

 Complex Colour
I)NiH2O4enaq2+A)Grey – green
II)NiH2O2en2aq2+B)Violet
III)Nien3aq2+C)Blue/Purple
IV)CrH2O5ClCl2.H2OD)Pale blue

The correct match is 

Easy
Solution

Colour of the complex depends on the nature and charge of metal ion, strength of ligand.

NiH2O6+2greenaq+enaqNiH2O4en+2paleblueaq+2H2ONiH2O4en+2 aq+enaqNiH2O2en2+2blue/purpleaq+2H2ONiH2O2en2+2 aq+enaqNien3+3violetaq+2H2OCrH2O6Cl3  is   violet;   CrH2O5ClCl2.H2O   is  greygreen


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