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Q.

Match the following List-I(Electronic config.)List II(Rules Violated)(A) I) Hund’s only(B) II) Pauli’s and Hund’s only(C) III) Auf-bau, Pauli’s and Hund’s(D) IV) Auf-bau onlyV)Auf-bau and Hund’s only

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a

A-I B-II C-V D-IV

b

A-II B-I C-IV D-III

c

A-II B-I C-V D-III

d

A-II B-I C-V D-IV

answer is A.

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Detailed Solution

Aufbau’s: Lower energy orbitals must be filled firstPauli’s: No two e- can have the same set of quantum numbersHund’s: Degenerate orbitals must be filled with e- with parallel spin

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