Match the inorganic compounds in List I with all characteristics of hydrolysis reactions and the products formed in List II

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P-2, Q-5, R-4, S-3

P-2,5; Q-1,2,4,5; R-2,3,4; S-2,3,5

P-1,3; Q-2,3; R-3,4; S-4

P-1,2; Q-1,3; R-1,4; S-2,5

answer is B.

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Detailed Solution

(1) Complete hydrolysis Hybridization of P in POCl3: sp3 Hybridization of P in H3PO4:sp3 H3PO4does not undergo tautomeric change due to absence of lone pair at P-atom.(2)Complete hydrolysisHF reacts with glassSiO2+4HF→ SiF4+2H2OHybridization of S-atom remains sp3(3) XeOF4+VI→−2HFH2OXeO2F2→H2OXeO3+VIXeOF4 can be partially hydrolysed to XeO2F2HF forms which reacts with glassHybridization Xe in XeOF4 in sp3d2 while in XeO3 it is sp3(4) H2S2O8+VI→H2OH2SO5+VI+H2SO4+VI→H2O2H2SO4+VI+H−O−O−HH2S2O8 can be partially hydrolysed to H2SO5Hybridization S-atom in H2S2O8 as well as in H2SO4 remains: sp3

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