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a
A - p,r ; B - p,r ; C - r,s ; D - p,q
b
A - q,s ; B - p,r ; C - q,s ; D - p,r
c
A - r,s ; B - p,r ; C - q,r ; D - p,q
d
A - p,q,r ; B - p,q,r ; C - r,s ; D - p,q
answer is B.
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Detailed Solution
A→q,s; B→p,r; C→q,s; D→p,rHexane and heptane; chlorobenzene and bromobenzene are the mixtures that form ideal solutions, i.e. they follow Raoult's law in all conditions of T and p.For such solutions. ΔHmix =0 and ΔVmix=0Mixture of chloroform with acetone and water with nitric acid show negative deviation from Raoult's law. So for these pairs. A−B>A−A or B−B interaction ΔVmix <0 and ΔHmix <0