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Q.

Match the items of Column I with Column II.

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a

A - p,r ; B - p,r ; C - r,s ; D - p,q

b

A - q,s ; B - p,r ; C - q,s ; D - p,r

c

A - r,s ; B - p,r ; C - q,r  ; D - p,q

d

A - p,q,r  ; B - p,q,r ; C - r,s ; D - p,q

answer is B.

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Detailed Solution

A→q,s; B→p,r; C→q,s; D→p,rHexane and heptane; chlorobenzene and bromobenzene are the mixtures that form ideal solutions, i.e. they follow Raoult's law in all conditions of T and p.For such solutions.                         ΔHmix =0 and ΔVmix=0Mixture of chloroform with acetone and water with nitric acid show negative deviation from Raoult's law. So for these pairs.              A−B>A−A or B−B interaction ΔVmix <0 and ΔHmix <0
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