Mechanism of a hypothetical reactionX2+Y2→2XYis given below :(i) X2→X+X(fast)(ii) X+Y2⇌XY+Y (slow)(iii) X + Y ➔ XY (fast)The overall order of the reaction will be
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answer is 3.
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Detailed Solution
Note : Correct the reactions given in question as X2⇌X+X (fast) X+Y2⟶XY+Y (Slow) Slow step is the rate determining step. Rate =K[X]Y2 (i) Equilibrium constant for fast step, K=[X]2X2 [X]=KX2 By substituting [X] in equation (i), we get Rate =kKX2Y2=k'X21/2Y2 ∴ Order of reaction =12+1=32=1.5