A metal M reacts with N2 to give a compound ‘A’ M3N. ‘A’ on heating at high temperature gives back ‘M’ and ‘A’ on reacting with H2O gives a gas ‘B’. ‘B’ turns CuSO4 solution blue on passing through it. A and B can be
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a
Al and NH3
b
Li and NH3
c
Na and NH3
d
Mg and NH3
answer is B.
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Detailed Solution
Lithium forms nitride on heating with nitrogen;Lithium nitride gives ammonia when heated with H2O. Ammonia gas forms tetrammine copper complex with CuSO4 solution.6Li + N2 → 2Li3N Li3N + 3H2O → 3LiOH + NH3 CuSO4 + 4NH3 → CuNH34SO4