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Q.

Methylene blue in aqueous solution, is adsorbed on activated charcoal at 25°C.For this process, the correct statement is

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a

The adsorption requires activation at 25°C

b

The adsorption is accompanied by a decrease in enthalpy

c

The adsorption increases with increase of temperature

d

The adsorption is irreversible

answer is B.

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Detailed Solution

Adsorption is  spontaneous (ΔG<0) andtakesplacewith  decrease in entropy (due to decrease in disorder). Thus, ΔS<0 Since,  ΔG=ΔH−TΔS⇒ΔH=(ΔG+TΔS) Since, both ΔG<0, and ΔS<0 Hence, ΔH<0 (exothermic) By Le-Chatelier's principle, increase in temperature, decreases adsorption.
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